Sun, May 3

A Hydrogen Curriculum for Mobility, Industry, and Grid Integration

Below some concise exercices, for different sectors, designed to help students understand how hydrogen can be integrated into transport, industry, and energy storage. Each includes a practical scenario and guiding questions.

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1) Transport: Hydrogen Fuel Cell Vehicles
Scenario:
A city plans to replace 100 diesel buses with hydrogen-powered buses using Hydrogen Fuel Cells.

Exercise: Each bus consumes 8 kg of hydrogen per day. Hydrogen has an energy content of ~33 kWh/kg.

Questions:
1. Calculate the total daily hydrogen demand for the fleet.
2. Estimate the total daily energy consumption (in kWh).
3. Compare this with diesel: if 1 diesel bus uses 40 liters/day (~10 kWh/liter), which system uses more energy?
4. Discuss two advantages and two challenges of switching to hydrogen in public transport.

Correction:
Step 1: Total hydrogen demand
Each bus uses 8 kg/day
Fleet = 100 buses
Total H₂=100×8=800 kg/day

Step 2: Total energy consumption
Hydrogen energy content = 33 kWh/kg
Energy=800×33=26,400 kWh/day

Step 3: Diesel comparison
Each diesel bus uses:
40 L/day × 10 kWh/L = 400 kWh/day
Fleet: 100×400=40,000 kWh/day

Step 4: Interpretation
Hydrogen fleet: 26,400 kWh/day
Diesel fleet: 40,000 kWh/day
--> Hydrogen appears to use less energy overall

BUT:
-Fuel cells are more efficient than combustion engines
-Diesel engines waste a lot of energy as heat

Step 5: Advantages vs challenges
Advantages:
-Zero tailpipe emissions (no CO₂, only water vapor)
-Higher efficiency than diesel engines
-Quiet operation and better air quality

Challenges:
- Hydrogen production is energy-intensive
- Lack of refueling infrastructure
- Storage and transport of hydrogen is complex

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2) Industry: Green Steel Production
Scenario:
A steel plant wants to replace coal with hydrogen in the Direct Reduction of Iron process.

Exercise:
To produce 1 ton of steel, about 50 kg of hydrogen is required.

Questions:
-How much hydrogen is needed to produce 1 million tons of steel annually?
-If hydrogen is produced via Electrolysis requiring ~50 kWh/kg, estimate total electricity demand.
-Compare CO₂ emissions between coal-based and hydrogen-based production.
-Identify one economic and one technical barrier to adopting hydrogen in steelmaking.

Step 1: Hydrogen requirement
1 ton steel → 50 kg H₂
1 million tons → 1,000,000×50=50,000,000 kg H₂/year
--> 50 million kg (50,000 tons) of hydrogen per year

Step 2: Electricity demand for hydrogen
Electrolysis requires 50 kWh/kg
50,000,000×50=2,500,000,000 kWh --> 2.5 TWh/year

Step 3: CO₂ emissions comparison
Coal-based steel:
~1.8–2.0 tons CO₂ per ton steel
1,000,000×1.9≈1.9 million tons CO₂/year

Hydrogen-based steel:
Near 0 CO₂ (if hydrogen is green)
--> Emissions reduction ≈ ~1.9 million tons CO₂/year

Step 4: Interpretation
This is a massive decarbonization impact, but requires:
- Huge electricity supply (2.5 TWh = large power plant output)
- Renewable energy to truly be “green”

Step 5: Barriers
-Economic: Green hydrogen is still expensive compared to coal
-Technical: Scaling electrolyzers and hydrogen infrastructure; Retrofitting existing steel plants

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3) Energy Storage: Power-to-Hydrogen-to-Power
Scenario:
A solar farm produces excess electricity that is stored as hydrogen and later converted back to electricity.

Exercise:
The system uses Power-to-Gas with:
-Electrolysis efficiency: 70%
-Fuel cell efficiency: 50%

Questions:
-If 1,000 kWh of solar electricity is used, how much energy is stored in hydrogen?
-How much electricity is recovered after conversion back?
-Calculate the round-trip efficiency.
-Discuss why hydrogen storage might still be useful despite efficiency losses.

Step 1: Energy stored as hydrogen
-Input electricity = 1,000 kWh
-Electrolysis efficiency = 70%
Stored energy=1000×0.7=700 kWh

Step 2: Energy recovered
Fuel cell efficiency = 50%
Recovered energy=700×0.5=350 kWh

Step 3: Round-trip efficiency
Efficiency = 35/1000 = 35%

Step 4: Interpretation
--> Only 35% of the original energy is recovered
--> 65% is lost in conversion steps
This is much lower than batteries (~80–90%)

Step 5: Why hydrogen storage still matters
Despite low efficiency, hydrogen is valuable because:

1. Long-term storage
-Batteries are better for hours/days
-Hydrogen works for weeks or seasons

2. Large-scale storage
Can store massive energy quantities (underground, tanks)

3. Grid balancing
Useful for intermittent renewables like solar and wind

4. Multi-sector use
Stored hydrogen can also be used in: Transport, Industry

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